(N 4-n-Butylpyridine-4-carbothioamide-κN 4)chloridobis(dimethylglyoximato-κ2 N,N′)cobalt(III) hemihydrate
نویسندگان
چکیده
The title compound, trans-[Co(C(4)H(7)N(2)O(2))(2)Cl(C(10)H(14)N(2)S)]·0.5H(2)O, contains two independent mol-ecules in the asymmetric unit in which the Co(III) ions are coordinated in slightly distorted octa-hedral coordination environments. The bis-chelating glyoximate ligands, which occupy equatorial sites, are linked by interligand O-H⋯O hydrogen bonds. The dihedral angles between the mean planes of the glyoximate ligands in each mol-ecule are 2.07 (8) and 1.60 (1)°. The asymmetric unit contains a solvent water mol-ecule which is disordered over two sites with refined occupancies 0.64 (2) and 0.36 (2).
منابع مشابه
Chloridobis(dimethylglyoximato-κ2 N,N′)(4-methylpyridine-κN)cobalt(III) hemihydrate
In the title complex, [Co(C(4)H(7)N(2)O(2))(2)Cl(C(6)H(7)N)]·0.5H(2)O, the central Co(III) ion, chelated by four N atoms of the two bidenate glyoximate ligands, exhibits a slightly distorted octa-hedral geometry. The axial positions are occupied by a chloride ion and the 4-methyl-pyridine N atom. Inter-molecular O-H⋯O hydrogen bonds link the mol-ecules in the crystal via the water mol-ecules, w...
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